Gao, Wen-Chao; Liu, Jianrong; Jiang, Xuefeng published an article in 2021, the title of the article was Phthalimide-based-SSCF3 reagent for enantioselective dithiotrifluoromethylation.Application In Synthesis of Methyl 2-cyclopentanonecarboxylate And the article contains the following content:
An electrophilic phthalimide-based-SSCF3 reagent was designed and prepared for straightforward SSCF3 incorporation of diverse β-keto esters in natural products, pharmaceuticals and biol. mols. The asym. dithiotrifluoromethylation was achieved with a good to excellent enantioselectivity, catalyzed by a cinchona-alkaloid-based catalyst (DHQD)2PHAL via an ammonium-hydrogen-bonded induction mode. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Application In Synthesis of Methyl 2-cyclopentanonecarboxylate
The Article related to indanone carboxylate dithiotrifluoromethyl phthalimide cinchona catalyst enantioselective dithiotrifluoromethylation, dithiotrifluoromethyl phthalimide indanone carboxylate dmap catalyst dithiotrifluoromethylation, trifluoromethyldisulfanyl indanone carboxylate preparation and other aspects.Application In Synthesis of Methyl 2-cyclopentanonecarboxylate
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