On February 13, 2019, Cao, Chen-Chen; Chen, Cheng-Xia; Wei, Zhang-Wen; Qiu, Qian-Feng; Zhu, Neng-Xiu; Xiong, Yang-Yang; Jiang, Ji-Jun; Wang, Dawei; Su, Cheng-Yong published an article.Related Products of 1312703-30-2 The title of the article was Catalysis through Dynamic Spacer Installation of Multivariate Functionalities in Metal-Organic Frameworks. And the article contained the following:
We demonstrate herein a facile strategy to engineer versatile catalytically active coordination interspace in the same primitive metal-organic framework (MOF) for variable heterogeneous catalysis. Different functional ligands can be reversibly inserted into and removed from proto-LIFM-28 individually or successively to bring in single or binary catalytic sites for specific reactions and switch the parent MOF to multipurpose catalysts. Alc.-oxidation, Knoevenagel-condensation, click, acetal, and Baylis-Hillman reactions are achievable through simple exchange of a single catalytic spacer, while sequential or stepwise reactions are designable via selective combination of two catalytic spacers with different functionalities, thus making proto-LIFM-28 a multivariate MOF for multiuse and economic catalysis. The experimental process involved the reaction of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate(cas: 1312703-30-2).Related Products of 1312703-30-2
The Article related to multivariate metal organic framework dynamic spacer installation preparation, sequential stepwise reaction mof catalyst, oxidation knoevenagel condensation click acetal baylis hillman reaction catalyst and other aspects.Related Products of 1312703-30-2
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