On August 18, 2017, Abe, Takumi; Suzuki, Takuro; Anada, Masahiro; Matsunaga, Shigeki; Yamada, Koji published an article.Recommanded Product: Methyl N-Methylanthranilate The title of the article was 2-Hydroxyindoline-3-triethylammonium Bromide: A Reagent for Formal C3-Electrophilic Reactions of Indoles. And the article contained the following:
A novel indole-2,3-epoxide equivalent, trans-2-hydroxyindoline-3-triethylammonium bromide (I), was found to be a convenient reagent for formal C3-electrophilic reactions of indoles with various nucleophiles. By taking advantage of the nucleophilic character of the oxygen of the 2-hydroxyindoline, the interrupted retro-Claisen and interrupted Feist-Benary reactions with 1,3-dicarbonyl compounds were efficiently achieved. The process was successfully applied to the synthesis of cryptolepine. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Recommanded Product: Methyl N-Methylanthranilate
The Article related to hydroxyindole triethylammonium bromide nucleophilic amination substitution indole, cryptolepine preparation, interrupted retro claisen hydroxyindole triethylammonium bromide dicarbonyl compound, feist benary interrupted hydroxyindole triethylammonium bromide cyclic diketone and other aspects.Recommanded Product: Methyl N-Methylanthranilate
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