Molle, Edgar; Frech, Stefan; Grueger, Tilman; Theato, Patrick published the artcile< Electrochemically-initiated polymerization of reactive monomers via 4-fluorobenzenediazonium salts>, Safety of Perfluorophenyl acrylate, the main research area is electrochem polymerization reactive monomer fluorobenzenediazonium salt.
The straightforward electrochem.-initiated radical polymerization of three reactive monomers, i.e. 2,6-difluorophenyl acrylate (DFPA), pentafluorophenyl acrylate (PFPA), and glycidyl methacrylate (GMA), using a simple com. available electrochem. setup for the generation of initiating radical species from 4-fluorobenzenediazonium tetrafluoroborate upon electrochem. cathodic reduction is reported. The use of a fluorine-labeled initiator allowed for the determination of number-average molar masses Mn of fluorine-containing polymers by 19F NMR spectroscopy in addition to size-exclusion chromatog. The obtained polymers were thereafter successfully subjected to post-polymerization modifications in order to emphasize the applicability of this polymerization method in regard to highly reactive monomers.
Polymer Chemistry published new progress about Acrylic polymers, fluorine-containing Role: PRP (Properties), SPN (Synthetic Preparation), PREP (Preparation). 71195-85-2 belongs to class esters-buliding-blocks, and the molecular formula is C9H3F5O2, Safety of Perfluorophenyl acrylate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics