Li, Fang-Fang; Ma, Jian-Fang; Song, Shu-Yan; Yang, Jin; Liu, Ying-Ying; Su, Zhong-Min published the artcile< Influence of Neutral Ligands on the Structures of Silver(I) Sulfonates>, Electric Literature of 112-63-0, the main research area is silver sulfonate pyrazine picoline hexamethylenetetramine complex preparation structure; crystal structure silver sulfonate pyrazine picoline hexamethylenetetramine complex.
This article represents a systematical examination of the structures of Ag(I) sulfonates incorporating neutral ligands. To survey the influence of the properties of neutral ligands on the structures of Ag(I) sulfonates, three kinds of sulfonate anions (L1 = 1-naphthalenesulfonate, L2 = p-toluenesulfonate, and L3 = 1,3,6,8-pyrenetetrasulfonate) and three kinds of neutral ligands (pyrazine, Pyr, a divergent bidentate ligand; hexamethylenetetramine, hmt, a divergent tetradentate ligand; and β-picoline, Pic, a monodentate ligand) were selected for study, and five novel Ag(I) sulfonates containing neutral ligands were synthesized: [Ag(L1)(Pyr)]·H2O (1), Ag(L2)(Pyr) (2), Ag4(L3)(Pyr)4(H2O)2 (3), [Ag(L1)(hmt)]·H2O (4), and Ag(L1)(Pic)2 (5). The crystal structures were determined by single-crystal x-ray diffraction, and these compounds show a variety of structures with different dimensionalities. Also, the luminescent properties of compounds 2, 4 and 5 are also discussed.
Inorganic Chemistry published new progress about Crystal structure. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Electric Literature of 112-63-0.
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