Jagleniec, Damian; Wilczek, Marcin; Romanski, Jan published the artcile< Tripodal, squaramide-based ion pair receptor for effective extraction of sulfate salt>, Computed Properties of 112-63-0, the main research area is tripodal squaramide based ion pair receptor preparation; ion pair receptors; squaramide; sulfate extraction; tripodal receptors.
Combining three features-the high affinity of squaramides toward anions, cooperation in ion pair binding and preorganization of the binding domains in the tripodal platform-led to the effective receptor I [R1R2 = O(CH2CH2O)5]. The lack of at least one of these key elements caused a lower affinity toward ion pairs. Receptor I [R1R2 = O(CH2CH2O)5] was found to form an intramol. network in wet chloroform, which changed into inorganic-organic associates after contact with ions and allowed salts to be extracted from an aqueous to an organic phase. The disparity in the binding mode of I [R1R2 = O(CH2CH2O)5] with sulfates and with other monovalent anions led to the selective extraction of extremely hydrated sulfate anions in the presence of more lipophilic salts, thus overcoming the Hofmeister series.
Molecules published new progress about Crown ethers Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics