Dayaker, Gandrath’s team published research in Helvetica Chimica Acta in 2014-06-17 | 617-55-0

Helvetica Chimica Acta published new progress about Alkenylation. 617-55-0 belongs to class esters-buliding-blocks, and the molecular formula is C6H10O5, Formula: C6H10O5.

Dayaker, Gandrath; Krishna, Palakodety Radha published the artcile< Olefin Cross-Metathesis: Studies towards the Total Synthesis of (+)-Bitungolide F>, Formula: C6H10O5, the main research area is bitungolide preparation total synthesis.

S stereoselective synthesis of (5S,6S)-6-[(2S,5S,7R,8E,10E)-5-(benzyloxy)-7-{[(tert-butyl)dimethylsilyl]oxy}-11-phenylundeca-8,10-dien-2-yl]-5-ethyl-5,6-dihydro-2H-pyran-2-one [i.e., 9-O-benzyl-11-O-[(tert-butyl)dimethylsilyl]bitungolide F] is reported. The strategy involves Gilman reaction, olefin cross-metathesis, and Horner-Wadsworth-Emmons olefination as key steps. The synthesis of the target compound was achieved using((2S)-2-(hydroxy)butanedioic acid (L-malic acid) as a simple starting material.

Helvetica Chimica Acta published new progress about Alkenylation. 617-55-0 belongs to class esters-buliding-blocks, and the molecular formula is C6H10O5, Formula: C6H10O5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics