Chen, Xingkuan; Fang, Xinqiang; Chi, Yonggui Robin published the artcile< cis-Enals in N-heterocyclic carbene-catalyzed reactions: distinct stereoselectivity and reactivity>, Reference of 112-63-0, the main research area is enal imine cyclization heterocyclic carbene; cyclic ketone stereoselective preparation; heterocyclic carbene stereoselective cyclization catalyst.
The first successful generation of cis-homoenolate equivalent from cis-enals under the catalysis of N-heterocyclic carbenes (NHCs) has been realized. The cis-homoenolate intermediates undergo effective reactions with α,β-unsaturated imines to afford chiral cyclic ketone products, e.g., I and II. Compared to the trans-enals, cis-enals show different stereoselectivities and new reactivity patterns.
Chemical Science published new progress about Cyclic ketones Role: SPN (Synthetic Preparation), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Reference of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics