Lokhov, R. E. published the artcile< Kinetics of N-oxidation of compounds of the quinoline series and isomeric benzoquinolines by perbenzoic acid in chloroform and aqueous dioxane>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is oxidation quinoline benzoquinoline peroxybenzoic acid.
Rate constants and activation parameters were determined for the title reactions; a bimol. mechanism was indicated. Annelation of pyridine lowered its oxidation rate. The rate constant for oxidation of 4-amino-2,3-benzoquinoline was nearly an order of magnitude higher in CHCl3 than in aqueous dioxane. Correlations with nucleophilicity parameters and half-wave potentials for the reduction of the azine cations were discussed. The electron d. at N had a small effect; π conjugation between the substituent and the reaction center was an important factor.
Khimiya Geterotsiklicheskikh Soedinenii published new progress about Nucleophilicity. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics