Liu, Jing; Wan, Cong; Zheng, Aili; Wang, Lianyue; Yin, Kaiyue; Liu, Dandan; Wang, Shengde; Ren, Lanhui; Gao, Shuang published the artcile< α-Oxygenation of Benzylic Ethers to Esters Using MnOx-N@C Catalyst>, Category: esters-buliding-blocks, the main research area is benzoic ester preparation chemoselective green chem; benzylic ether oxidation manganese catalyst.
A catalytic system for the oxidation of benzylic ethers 2-R-3-R1-4-R2-5-R3-6-R4C6CH2OR5 (R = H, OH, Cl, OMe, etc.; R1 = H, Me, OMe, CF3; RR1 = -CH=CH-CH=CH-; R2 = H, i-Pr, Cl, Ph, etc.; R1R2 = -OCH2O-; R3 = H; R4 = H, Cl; R3R4 = -CH=CH-CH=CH-; R5 = Me, Et, Bn; R4R5 = -(CH2)2-, -CH2-) to esters 2-R-3-R1-4-R2-5-R3-6-R4C6C(O)OR5 has been developed utilizing reusable MnOx-N@C as catalyst and tert-Bu hydroperoxide (TBHP) as benign oxidant under neat condition. The catalytic oxidation system has good functional groups tolerance and excellent chemoselectivity, and this catalytic procedure can also be scaled up.
Youji Huaxue published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 2557-13-3 belongs to class esters-buliding-blocks, and the molecular formula is C9H7F3O2, Category: esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics