Xu, Zhengren; Wang, Qian; Zhu, Jieping published the artcile< Palladium-Catalyzed Decarboxylative Vinylation of Potassium Nitrophenyl Acetate: Application to the Total Synthesis of (±)-Goniomitine>, Product Details of C9H9NO4, the main research area is vinylation palladium catalyst decarboxylative potassium nitrophenyl acetate; goniomitine total synthesis decarboxylative vinylation potassium nitrophenyl acetate; oxidation reduction cyclization stereoselective total synthesis goniomitine.
A seven step total synthesis of (±)-goniomitine has been accomplished via novel palladium-catalyzed decarboxylative coupling of potassium nitrophenyl acetates and vinyl triflates and a one-pot multiple bond forming integrated oxidation/reduction/cyclization process. Thus, reacting potassium (2-nitrophenyl)acetate with cyclohex-1-en-1-yl triflate in the presence of [{PdCl(allyl)}2]/XPhos in DMF gave 1-[(2-nitrophenyl)methyl]-1-cyclohexene.
Angewandte Chemie, International Edition published new progress about Cyclization, stereoselective. 30095-98-8 belongs to class esters-buliding-blocks, and the molecular formula is C9H9NO4, Product Details of C9H9NO4.
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