Eberhardt, Marc; Mruk, Ralf; Zentel, Rudolf; Theato, Patrick published the artcile< Synthesis of pentafluorophenyl (meth)acrylate polymers: New precursor polymers for the synthesis of multifunctional materials>, COA of Formula: C9H3F5O2, the main research area is pentafluorophenyl acrylate methacrylate polymerization amine alc reactivity multifunctional polymer.
Pentafluorophenyl acrylate and -methacrylate were polymerized using AIBN as a thermal initiator. The obtained polymers were soluble polymeric active esters that could be used for the preparation of multifunctional polymers. The reactivity of poly(pentafluorophenyl acrylate) and poly(pentafluorophenyl methacrylate) towards primary and secondary amines, as well as alcs. was investigated in a quant. way. Both poly(active esters) reacted satisfactorily with aliphatic primary and secondary amines but only low conversion was found in the case of aromatic amines. Conversions of only 30% were reached when poly(pentafluorophenyl acrylate) was treated with one equivalent of alc. under base catalysis. In time resolved FT-IR studies the rate constants of the polymer analogous reactions were determined
European Polymer Journal published new progress about Fluoropolymers Role: SPN (Synthetic Preparation), PREP (Preparation). 71195-85-2 belongs to class esters-buliding-blocks, and the molecular formula is C9H3F5O2, COA of Formula: C9H3F5O2.
Referemce:
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