Ouyang, Jia-Sheng; Li, Yan-Fang; Huang, Fei-Dong; Lu, Dong-Dong; Liu, Feng-Shou published the artcile< The Highly Efficient Suzuki-Miyaura Cross-Coupling of (Hetero)aryl Chlorides and (Hetero)arylboronic Acids Catalyzed by ''Bulky-yet-Flexible'' Palladium-PEPPSI Complexes in Air>, Quality Control of 112-63-0, the main research area is biphenyl preparation; chloride aryl boronic acid Suzuki Miyaura coupling palladium catalyst.
A series of Pd-PEPPSI complexes was designed and synthesized. The relationship between catalyst structure and properties was systematically investigated. It was revealed that “”bulky-yet-flexible”” C3 bearing acenaphthyl backbone was a highly efficient precatalyst and could be successfully employed in Suzuki-Miyaura reactions of (hetero)aryl chlorides ArCl (Ar = 4-CH3C6H4, pyridin-2-yl, thiophen-2-yl, etc.) with (hetero)arylboronic acids RB(OH)2 (R = C6H5, 2-OCH3C6H4, naphthalen-1-yl, etc.) at a low palladium loading in the presence of a weak inorganic base in air.
ChemCatChem published new progress about Aryl chlorides Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Quality Control of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics