Miki, Akinori; Nishikawa, Kei; Kamesui, Go; Matsushima, Hisayoshi; Ueda, Mkito; Rosso, Michel published the artcile< In situ interferometry study of ionic mass transfer phenomenon during the electrodeposition and dissolution of Li metal in solvate ionic liquids>, Application In Synthesis of 112-63-0, the main research area is interferometry ionic mass transfer electrodeposition dissolution lithium ionic liquid.
A digital holog. microscope was used to observe the Li+ concentration profile in situ, accompanied by the electrodeposition and electrochem. dissolution of Li metal in a solvate ionic liquid The concentration profile showed a linear relation with the square root of time in a quasi-two-dimensional electrochem. cell that could restrict natural convection fluid motion. For the anodic reaction, the electrochem. dissolution of Li metal induced an increase in concentration in the vicinity of the anode surface. Solvate ionic liquids have an enormous Li salt concentration, and the concentration increase induces a drastic increase in the viscosity of the electrolyte, resulting in a change in cell voltage. In situ Raman spectroscopy supported the development of the concentration profile near the electrode surface. The coordination of the chem. species also changed with the development of concentration profile induced by electrodeposition and electrochem. dissolution of Li metal in the solvate ionic liquid This study emphasizes that the development of a concentration profile is more important for a concentrated electrolyte (e.g., solvated ionic liquid) than a conventional 1 M class battery electrolyte. This is because the concentration in the vicinity of the electrode can deviate from the ideal molar ratio of Li salt and solvents due to the electrochem. reaction.
Journal of Materials Chemistry A: Materials for Energy and Sustainability published new progress about Battery electrolytes. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Application In Synthesis of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics