Li, Jiagen; Wang, Ming; Jiang, Xuefeng published the artcile< Diastereoselective Synthesis of Thioglycosides via Pd-Catalyzed Allylic Rearrangement>, Formula: C12H16O7, the main research area is diosgenyl rhamnoside isoquercitrin rearrangement sulfoxide rhamnoside glucoside; stereoselective glycosylation thioglycosylation thioglycoside thiosulfate glycal; crystal structure stereoselective allylic rearrangement palladium catalyzed.
Stereoselective glycosylation is challenging in carbohydrate chem. Herein, stereoselective thioglycosylation of glycals via palladium-catalyzed allylic rearrangement yields various substituents on α-isomer thioglycosides. Two comprehensive series of aryl and benzyl thioglycosides were obtained via a combination of thiosulfates with glycals derived from glucose, arabinose, galactose, and rhamnose. Furthermore, diosgenyl α-L-rhamnoside and isoquercitrin achieved selectivity via stereospecific [2,3]-sigma rearrangements of α-sulfoxide-rhamnoside and α-sulfoxide-glucoside, resp.
Organic Letters published new progress about Crystal structure. 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Formula: C12H16O7.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics