Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. 870-50-8, formula is C10H18N2O4, Name is Di-tert-butyl diazene-1,2-dicarboxylate. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Reference of 870-50-8.
Wan, Ting;Wen, Zhenghui;Laudadio, Gabriele;Capaldo, Luca;Lammers, Rob;Rincon, Juan A.;Garcia-Losada, Pablo;Mateos, Carlos;Frederick, Michael O.;Broersma, Remy;Noel, Timothy research published 《 Accelerated and Scalable C(sp3)-H Amination via Decatungstate Photocatalysis using a Flow Photoreactor equipped with High-Intensity LEDs》, the research content is summarized as follows. Herein, the use of a newly developed flow photoreactor equipped with high intensity chip-on-board LED technol. (144 W optical power) to trigger the regioselective and scalable C(sp3)-H amination via decatungstate photocatalysis was reported. This high-intensity reactor platform enables simultaneously fast results gathering and scalability in a single device, thus bridging the gap between academic discovery (mmol scale) and industrial production (>2 kg/day productivity). The photocatalytic transformation was amenable to the conversion of both activated and nonactivated hydrocarbons, leading to protected hydrazine products by reaction with azodicarboxylates. It was further validated the robustness of our manifold by designing telescoped flow approaches for the synthesis of pyrazoles, phthalazinones and free amines.
870-50-8, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., Reference of 870-50-8
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics