Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. 870-50-8, formula is C10H18N2O4, Name is Di-tert-butyl diazene-1,2-dicarboxylate.Nitrate esters, such as nitroglycerin, are known for their explosive properties. Application In Synthesis of 870-50-8.
Trost, Barry M.;Tracy, Jacob S.;Lin, Eric Y. research published 《 Asymmetric Electrophilic Amination and Hydrazination of Acyclic α-Branched Ketones for the Formation of α-Tertiary Amines and Hydrazines》, the research content is summarized as follows. Chiral α-tertiary amines can be accessed directly through the electrophilic amination of α-branched ketones utilizing di-tert-Bu azodicarboxylate as the electrophilic nitrogen source. This process, catalyzed by a dinuclear zinc-prophenol complex, proceeds under mild reaction conditions and with a diverse range of vinyl ketones. The reactions can be run on gram-scale with reduced catalyst loadings and feature a recoverable ligand. The hydrazine products are shown to undergo chemoselective N-N bond cleavage without reduction of the α,β-unsaturated ketone, revealing chiral α-amino ketones.
870-50-8, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., Application In Synthesis of 870-50-8
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics