Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. 870-50-8, formula is C10H18N2O4, Name is Di-tert-butyl diazene-1,2-dicarboxylate. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Reference of 870-50-8.
Ruan, Sai;Zhong, Xia;Chen, Quangang;Feng, Xiaoming;Liu, Xiaohua research published 《 An asymmetric hydrocyanation/Michael reaction of α-diazoacetates via Cu(I)/chiral guanidine catalysis》, the research content is summarized as follows. An asym. one-pot hydrocyanation/Michael reaction of α-aryl diazoacetates ArC(N2)C(O)2R1 (Ar = Ph, 4-fluorophenyl, naphthalen-2-yl, etc.; R1 = Me, Et, i-Pr) with trimethylsilyl cyanide, tert-butanol, and maleimides I (R2 = Me, benzyl, 2-fluorophenyl, etc.) has been realized. Using a chiral guanidinium salt/CuBr catalyst, a series of cyanide-containing pyrrolidine-2,5-diones II could be obtained in good yields with excellent diastereo- and enantioselectivities.
870-50-8, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., Reference of 870-50-8
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics