Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. 99769-19-4, formula is C8H9BO4, Name is 3-(Methoxycarbonyl)phenylboronic acid.Nitrate esters, such as nitroglycerin, are known for their explosive properties. Recommanded Product: 3-(Methoxycarbonyl)phenylboronic acid.
Kletskov, Alexey V.;Bumagin, Nikolay A.;Petkevich, Sergey K.;Dikusar, Evgenij A.;Lyakhov, Alexander S.;Ivashkevich, Ludmila S.;Kolesnik, Iryna A.;Potkin, Vladimir I. research published 《 Mimics of Pincer Ligands: An Accessible Phosphine-Free N-(Pyrimidin-2-yl)-1,2-azole-3-carboxamide Framework for Binuclear Pd(II) Complexes and High-Turnover Catalysis in Water》, the research content is summarized as follows. The authors report for the first time cyclic phosphine-free “head to tail” N,N,N pincer-like (pincer complexes mimicking) N-(pyrimidin-2-yl)-1,2-azole-3-carboxamide Pd(II) complexes with deprotonated amide groups as high-turnover catalysts (TON up to 106, TOF up to 1.2 × 107 h-1) for cross-coupling reactions on the background of up to quant. yields under Green Chem. conditions. The potency of the described catalyst family representatives was demonstrated in Suzuki-Miyaura, Mizoroki-Heck, and Sonogashira reactions on industrially practical examples. Corresponding ligands could be synthesized based on readily available reagents through simple chem. transformations. Within the complex structures, a highly unusual 1,3,5,7-tetraza-2,6-dipalladocane frame could be observed First representatives of a previously undescribed phosphine-free family of pyrimidine-azole mimics of pincer ligands give self-assembling binuclear Pd(II) complexes, efficient catalysts for C-C cross-coupling reactions. Ligands were synthesized via simple chem. reactions and from accessible reagents. Reactions proceed in water with remarkable TON (up to 106) and TOF (up to 1.2 × 107 h-1) on the background of up to quant. yields (demonstrated on industrially practical examples). First x-ray structure for an unusual 1,3,5,7-tetraza-2,6-dipalladocane frame was revealed.
99769-19-4, 3-Methoxycarbonylphenylboronic acid is a useful research compound. Its molecular formula is C8H9BO4 and its molecular weight is 179.97 g/mol. The purity is usually 95%.
3-Methoxycarbonylphenylboronic acid is a reactanct that has been involved in a variety of applications. For instance, it has been used in Suzuki-Miyaura cross-coupling, Iterative cross-coupling of boronate building blocks, cross-coupling with aryl/ alkenyl sulfonates, synthesis of symmetrical biaryls via CuCl catalyzed homocoupling, trifluoromethylation, and cyanation just to name a few of its many uses.
3-Methoxycarbonylphenylboronic acid is a boronate ligand that has been shown to have an interaction with the nitrogen atoms in amines. This compound is used for the Suzuki coupling reaction, which is a chemical reaction between an organoboron compound and an organic electrophile. 3-Methoxycarbonylphenylboronic acid has a helical structure that can be seen by FTIR spectroscopy and it has potent inhibitory activity., Recommanded Product: 3-(Methoxycarbonyl)phenylboronic acid
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