On March 15, 2021, Meninno, Sara; Villano, Rosaria; Lattanzi, Alessandra published an article.Name: Methyl 2-cyclopentanonecarboxylate The title of the article was Magnesium Monoperphthalate (MMPP): a Convenient Oxidant for the Direct Rubottom Oxidation of Malonates, β-Keto Esters, and Amides. And the article contained the following:
A mild and convenient protocol for the α-hydroxylation of α-substituted malonates, β-ketoesters, and β-ketoamides is disclosed. Cheap and stable magnesium monoperphthalate (MMPP) was effective for a first direct α-hydroxylation protocol of the Rubottom oxidation, providing tartronic esters, cyclic α-hydroxy β-ketoesters and amides in good to high yields, when working at room temperature and in ethanol as the solvent. The protocol has been successfully scaled up to gram quantity. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Name: Methyl 2-cyclopentanonecarboxylate
The Article related to malonate magnesium monoperphthalate regioselective rubottom hydroxylation, ketoester magnesium monoperphthalate regioselective rubottom hydroxylation, ketoamide magnesium monoperphthalate regioselective rubottom hydroxylation, hydroxy malonate ketoester ketoamide preparation and other aspects.Name: Methyl 2-cyclopentanonecarboxylate
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