Luecke, Daniel; Kalesse, Markus published an article in 2019, the title of the article was Polyoxygenated Tertiary Alcohols: A Kiyooka Approach.Recommanded Product: 3976-69-0 And the article contains the following content:
A Kiyooka aldol approach for the stereoselective synthesis of tertiary alcs. I (R = (2R)-3-[(4-methoxyphenyl)methoxy]-2-methylpropyl, (2R)-2-[(4-methoxyphenyl)methoxy]propyl, (2S,3R)-3-[(4-methoxyphenyl)methoxy]-2-methylbutyl, (2R,3R)-3-[(4-methoxyphenyl)methoxy]-2-methylbutyl; R1 = C(O), CH-OTBS) is presented. This approach allows for the incorporation of different substituents at all three remaining positions at the chiral center bearing the tertiary alc.I. To demonstrate the validity of this approach different chiral alcs. I were depicted and the relationship of double bond geometry of the ketene acetal II and the diastereoselectivity was established. The experimental process involved the reaction of (R)-Methyl 3-hydroxybutanoate(cas: 3976-69-0).Recommanded Product: 3976-69-0
The Article related to tertiary alc preparation enantioselective diastereoselective, tertbutyldimethylsilyl protected hemiacetal preparation enantioselective diastereoselective, chiral aldehyde ketene acetal kiyooka aldol reaction, aldol reaction, chiral aldehydes, double bond geometry, ketene acetal, structure elucidation and other aspects.Recommanded Product: 3976-69-0
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