On October 1, 2015, Lin, Wenbin; Manna, Kuntal; Zhang, Teng published a patent.Synthetic Route of 1312703-30-2 The title of the patent was Preparation of metal-organic frameworks containing nitrogen-donor ligands for efficient catalytic organic transformations. And the patent contained the following:
Metal-organic framework (MOFs) compositions based on nitrogen donor-based organic bridging ligands, including ligands based on 1,3-diketimine (NacNac), bipyridines and salicylaldimine, were synthesized and then post-synthetically metalated with metal precursors, such as complexes of first row transition metals. Metal complexes of the organic bridging ligands could also be directly incorporated into the MOFs. The MOFs provide a versatile family of recyclable and reusable single-site solid catalysts for catalyzing a variety of asym. organic transformations. The solid catalysts can also be integrated into a flow reactor or a supercritical fluid reactor. For example, complex MOF [Zr6(OH)4O4L6] (bpy-UiO) (H2L = 2,2′-bipyridine-5,5′-dicarboxylic acid) is synthesized by reaction of ZrCl4 and H2L in DMF. The complex is used as catalyst for C-H borylation of arenes. Gas adsorption of the complex is measured as well. The experimental process involved the reaction of Dimethyl 2′-amino-[1,1′:4′,1”-terphenyl]-4,4”-dicarboxylate(cas: 1312703-30-2).Synthetic Route of 1312703-30-2
The Article related to transition metal oxo hydroxy bipyridinedicarboxylato complex catalyst preparation, gas adsorption transition metal oxo hydroxy bipyridinedicarboxylato complex, crystal structure transition metal oxo hydroxy bipyridinedicarboxylato complex, silylation hydrogenation catalyst transition metal oxo hydroxy bipyridinedicarboxylato complex and other aspects.Synthetic Route of 1312703-30-2
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