On April 9, 2014, Falkowski, Joseph M.; Sawano, Takahiro; Zhang, Teng; Tsun, Galen; Chen, Yuan; Lockard, Jenny V.; Lin, Wenbin published an article.Electric Literature of 3976-69-0 The title of the article was Privileged Phosphine-Based Metal-Organic Frameworks for Broad-Scope Asymmetric Catalysis. And the article contained the following:
A robust and porous Zr metal-organic framework (MOF) based on a BINAP-derived dicarboxylate linker, BINAP-MOF, was synthesized and post-synthetically metalated with Ru and Rh complexes to afford highly enantioselective catalysts for important organic transformations. The Rh-functionalized MOF is not only highly enantioselective (up to >99% ee) but also 3 times as active as the homogeneous control. XAFS studies revealed that the Ru-functionalized MOF contains Ru-BINAP precatalysts with the same coordination environment as the homogeneous Ru complex. The post-synthetically metalated BINAP-MOFs provide a versatile family of single-site solid catalysts for catalyzing a broad scope of asym. organic transformations, including addition of aryl and alkyl groups to α,β-unsaturated ketones and hydrogenation of substituted alkene and carbonyl compounds The experimental process involved the reaction of (R)-Methyl 3-hydroxybutanoate(cas: 3976-69-0).Electric Literature of 3976-69-0
The Article related to preparation ruthenium rhodium zirconium carboxyphenylethynyl binap hydroxo oxo framework, hydrogenation enantioselective catalyst ruthenium rhodium zirconium binap derivative framework, alkylation enantioselective catalyst ruthenium rhodium zirconium binap derivative framework and other aspects.Electric Literature of 3976-69-0
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