On April 25, 2020, Escobar, Randolph A.; Johannes, Jeffrey W. published an article.Application In Synthesis of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate The title of the article was A Unified and Practical Method for Carbon-Heteroatom Cross-Coupling using Nickel/Photo Dual Catalysis. And the article contained the following:
A general method that allows for C-O, C-N and C-S cross-coupling reactions under one general set of conditions has been described. An energy transfer pathway, in which an iridium photosensitizer produces an excited nickel(II) complex, is responsible for the key reductive elimination step that couples aryl halides RX (R = C6H5, 4-CF3C6H4, 3-pyridyl, etc.; X = Cl, Br, I) to 1° R1CH2OH (R1 = C6H5, 2-thienyl, 3-pyridyl, etc.) and 2° alcs. R2R3CHOH (R2 = Me, (CH2)2CH3, C6H5; R3 = Me; R2R3 = -(CH2)5-, R2R3 = -(CH2)4-, R2R3 = -(CH2)3-), amines R4NH2 (R4 = (CH2)3CH3, C6H5, 2-naphthyl, etc.) and 1-phenylethan-1-amine, thiols R5SH (R5 = C6H5, 2-naphthyl, cyclopentyl, etc.), carbamates R6OC(O)NH2 (R6 = t-Bu, Bn, allyl), and benzenesulfonamide, and is amenable to scale up via a flow app has been discussed. The experimental process involved the reaction of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate(cas: 141940-37-6).Application In Synthesis of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate
The Article related to ether preparation, alc aryl halide cross coupling nickel iridium dual photocatalyst, amine aryl halide cross coupling nickel iridium dual photocatalyst, thiol aryl halide cross coupling nickel iridium dual photocatalyst, carbamate aryl halide cross coupling nickel iridium dual photocatalyst, cross-coupling, dual catalysis, nickel catalysis, photocatalysis and other aspects.Application In Synthesis of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate
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