Zhang, Fangcao; Gong, Mingliang; Xie, Hongzhen; Luo, Yunjie published their research in New Journal of Chemistry in 2021. The article was titled 《La(CH2C6H4NMe2-o)3-catalyzed reduction of esters to alcohols with pinacolborane》.Product Details of 403-33-8 The article contains the following contents:
La(CH2C6H4NMe2-o)3, a simple and facilely accessible lanthanide complex, can serve as a highly efficient catalyst for the reduction of esters e.g., Me 4-(trifluoromethyl)benzoate with pinacolborane (HBpin), selectively affording alcs. e.g., [4-(trifluoromethyl)phenyl]methanol in good yields under mild conditions. This protocol exhibits good tolerance for many functional groups such as C=C double bond, nitro, halogen, furyl, and thienyl groups. A lanthanum hydride species like [La]-H.HBpin is proposed to play a crucial role in promoting the interaction of esters with HBpin. In the experiment, the researchers used Methyl 4-fluorobenzoate(cas: 403-33-8Product Details of 403-33-8)
Methyl 4-fluorobenzoate(cas: 403-33-8) is an organic fluorinated building block used for the synthesis of various pharmaceutical compounds. It can be used for the preparation of Blonanserin.Product Details of 403-33-8
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics