Synthetic Route of C8H14O4In 2019 ,《Ligand-Free, Quinoline N-Assisted Copper-Catalyzed Nitrene Transfer Reaction To Synthesize 8-Quinolylsulfimides》 appeared in Journal of Organic Chemistry. The author of the article were Xiao, Xinsheng; Huang, Sanping; Tang, Shanshan; Jia, Guokai; Ou, Guangchuan; Li, Yangyan. The article conveys some information:
In the presence of CuCN, 8-quinolinyl thioethers underwent regioselective imination via nitrene transfer reactions with sulfonyl azides to yield 8-quinolinyl sulfimides such as I (R = 4-MeC6H4, Ph, 4-ClC6H4, 4-BrC6H4, 4-F3CC6H4, 4-MeOC6H4, 4-MeCONHC6H4, 2-MeC6H4, 3-MeC6H4, 2,3,5,6-Me4C6H, 1-naphthyl, 2-thienyl, PhCH2, Me). I (R = 4-MeC6H4) was an effective ligand for allylic alkylation reactions of (E)-PhCH(OAc)CH:CHPh with 1,3-dicarbonyl compounds in the presence of PdCl2, N,O-bis(trimethylsilyl)acetamide, and KOAc. In the part of experimental materials, we found many familiar compounds, such as Diethyl 2-methylmalonate(cas: 609-08-5Synthetic Route of C8H14O4)
Diethyl 2-methylmalonate(cas: 609-08-5) belongs to aliphatic hydrocarbons. Aliphatic hydrocarbons belong to the most abundant fraction in crude oil. Aliphatics molecules are linear or branched open-chain structures such as n-alkanes, isoalkanes, cycloalkanes (naphthenes), terpenes and steranes.Synthetic Route of C8H14O4
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics