Li, Cheng-Kun; Tao, Ze-Kun; Zhou, Zhi-Hao; Bao, Xiao-Guang; Zhou, Shao-Fang; Zou, Jian-Ping published the artcile< Copper-Catalyzed Oxidative sp3-Carbon Radical Cross-Coupling with Trialkylphosphites Leading to α-Phosphonyl 1,3-Dicarbonyl Compounds>, Quality Control of 94-02-0, the main research area is copper catalyzed oxidative cross coupling alkylphosphite dicarbonyl compound; diketone alpha phosphonyl derivative preparation; ketoester alpha phosphonyl derivative preparation.
A Cu-catalyzed radical Csp3-H/P(OR)3 cross-coupling reaction for the formation of Csp3-P bonds is described. A range of 1,3-dicarbonyl compounds and trialkylphosphites were coupled in this fashion to give the corresponding products in moderate to good yields. This protocol provides direct access to α-phosphonyl 1,3-dicarbonyl compounds
Journal of Organic Chemistry published new progress about 1,3-Dicarbonyl compounds Role: RCT (Reactant), RACT (Reactant or Reagent). 94-02-0 belongs to class esters-buliding-blocks, and the molecular formula is C11H12O3, Quality Control of 94-02-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics