In 2022,Lessard, Jacob J.; Kaur, Parmeet; Paul, Justine E.; Chang, Kelly M.; Sottos, Nancy R.; Moore, Jeffrey S. published an article in ACS Macro Letters. The title of the article was 《Switching Frontal Polymerization Mechanisms: FROMP and FRaP》.Formula: C10H10O2 The author mentioned the following in the article:
Two frontal polymerization (FP) mechanisms, frontal ring-opening metathesis polymerization (FROMP) of dicyclopentadiene and frontal radical polymerization (FRaP) of benzyl acrylate and hexanediol diacrylate, were combined for rapid manufacturing of welded thermoset materials. Leveraging the immiscibility of the two different FP resins, welded thermosets and gradient foams of varying composition were achieved by switching of FP mechanisms. The adhesion strength of the welded thermoset materials differed depending on the originating mechanism. Finally, welded thermoset foams of varying porosity and homogeneity were generated through initiation from the bottom of the two resins. In the part of experimental materials, we found many familiar compounds, such as Benzyl acrylate(cas: 2495-35-4Formula: C10H10O2)
Benzyl acrylate(cas: 2495-35-4) has been used in preparation of high refractive index polyacrylates. Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.Formula: C10H10O2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics