Guo, Hong-Mei; Wu, Xuesong published their research in Nature Communications in 2021. The article was titled 《Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations》.Recommanded Product: 2495-35-4 The article contains the following contents:
A one-pot strategy for deoxygenative Giese reaction of alcs. with electron-deficient alkenes, by using xanthate salts as alc.-activating groups for radical generation under visible-light photoredox conditions in the presence of triphenylphosphine were reported. The convenient generation of xanthate salts and high reactivity of sequential C-S/C-O bond homolytic cleavage enable efficient deoxygenation of primary, secondary and tertiary alcs. with diverse functionality and structure to generate the corresponding alkyl radicals, including Me radical. Moreover, chemoselective radical monodeoxygenation of diols was achieved via selective formation of xanthate salts. In the experiment, the researchers used many compounds, for example, Benzyl acrylate(cas: 2495-35-4Recommanded Product: 2495-35-4)
Benzyl acrylate(cas: 2495-35-4) has been used in preparation of high refractive index polyacrylates. Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.Recommanded Product: 2495-35-4
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics