Fernandes, Alessandra A. G.; Stivanin, Mateus L.; Jurberg, Igor D. published the artcile< RuCl3/ PPh3 - Catalyzed Direct Conversion of Isoxazol-5-ones to 2,3-Disubstituted Pyridines>, Category: esters-buliding-blocks, the main research area is isoxazolone acrolein ruthenium chloride triphenyl phosphine catalyst decarboxylative heterocyclization; pyridine preparation.
A novel catalytic system employing RuCl3/ PPh3 was described for the preparation of 2,3-disubstituted pyridines starting from 3,4-disubstituted isoxazol-5-ones and acrolein. Mechanistic studies involving 31P NMR, HRMS analyses and control experiments were performed in order to supported key events and intermediates proposed for this transformation.
ChemistrySelect published new progress about Benzaldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 94-02-0 belongs to class esters-buliding-blocks, and the molecular formula is C11H12O3, Category: esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics