Application In Synthesis of Ethyl propiolateIn 2021 ,《A new metal-organic framework of 3,9-diazatetraasterane-1,5,7,11-tetracarboxylic acid-3,6,9,12-tetraphenyl with sodium ion: Synthesis, characterization and DFT calculations》 was published in Chemical Physics Letters. The article was written by Fan, Qiangwen; Zhu, Longwei; Ren, Huijun; Lin, Hailu; Wu, Guorong. The article contains the following contents:
A new three-dimensional metal-organic framework with regular 1-dimensional channel, [Na2(DATA)1/2(H2O)2·H2O]n, NaTADA, was synthesized by solvothermal reaction of 3,9-diazatetraasterane-1,5,7,11-tetracarboxylic acid-3,6,9,12-tetraphenyl (DATAH4) with sodium hydroxide, and characterized by x-ray single-crystal diffraction, TGA and FTIR spectroscopy. Besides, electronic structures anal., including mol. frontier orbitals, mol. electrostatic potential surface distribution, were also performed basing on electronic wavefunction obtained at the same calculated level for revealing intrinsic mol. structural characteristics. The experimental process involved the reaction of Ethyl propiolate(cas: 623-47-2Application In Synthesis of Ethyl propiolate)
Ethyl propiolate(cas: 623-47-2) is a clear colorless to pale yellow liquid that is soluble in ethanol, ether and chloroform. It an important organic chemical raw material and pharmaceutical intermediate. Ethyl propargylate is obtained by oxidation of propargyl alcohol to propargylic acid followed by esterification.Application In Synthesis of Ethyl propiolate
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