In 2022,Peng, Wei-Yu; Lan, Jian; Zhu, Zheng-Mei; Si, Li-Ping; Zhang, Hao; Zhan, Shu-Zhong; Liu, Hai-Yang published an article in Inorganic Chemistry Communications. The title of the article was 《Synthesis of metal (Ga, Co and Fe) 5,15-bis(pentafluorophenyl)-10-ethoxycarbonylcorrole and their electrocatalytic hydrogen evolution activity》.Computed Properties of C4H5ClO3 The author mentioned the following in the article:
5,15-Bis(pentafluorophenyl)-10-ethoxycarbonylcorrole and their metal complexes (metal = Ga, Co, Fe) had been synthesized and characterized (new complexes). These metal complexes had been used as electrocatalysts for hydrogen evolution reaction (HER) in organic acid and aqueous medium, in which the gallium corrole was firstly used for HER. The results showed that the redox potential of central metal atom for metal-centered metal (eg. Co and Fe) corroles plays a significant role in adjusting catalytic HER activity. Gallium corrole is a ligand-centered HER catalyst, the electronic structure of corrole ligand may play a key role in controlling the electrocatalytic activity. In the experiment, the researchers used many compounds, for example, Ethyl oxalyl monochloride(cas: 4755-77-5Computed Properties of C4H5ClO3)
Ethyl oxalyl monochloride(cas: 4755-77-5) belongs to acyl chlorides. In the laboratory, acyl chlorides are generally prepared by treating carboxylic acids with thionyl chloride (SOCl2). The reaction is catalyzed by dimethylformamide and other additives.Computed Properties of C4H5ClO3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics