Perez, Jesus de Maria’s team published research in Organic Chemistry Frontiers in 2021 | CAS: 51857-17-1

N-Boc-1,6-Diaminohexane(cas: 51857-17-1) is used to prepare 1,3-Bis[6-(Boc-amino)hexyl]urea by reacting with carbonyl dichloride in the presence of triethylamine. Further, it is used as a reagent for the introduction of a C6-spacer.Recommanded Product: N-Boc-1,6-Diaminohexane

Recommanded Product: N-Boc-1,6-DiaminohexaneIn 2021 ,《Mechanical bonding activation in rotaxane-based organocatalysts》 was published in Organic Chemistry Frontiers. The article was written by Perez, Jesus de Maria; Puigcerver, Julio; Orlando, Tainara; Pastor, Aurelia; Martins, Marcos A. P.; Alajarin, Mateo; Martinez-Cuezva, Alberto; Berna, Jose. The article contains the following contents:

Herein the enhanced efficiency as organocatalysts of a series of succinamide-based hydrogen-bonded [2]rotaxanes functionalized with an acyclic secondary amine as the catalytically active site was reported. Their catalytic activity was also evaluated by, comparing with that of their non-interlocked threads, in an iminium-type process between crotonaldehyde and acetylacetone. The presence of an interlocked polyamide macrocycle notably increased the catalytic activity of the entwined organocatalysts. The mechanized catalysts rapidly form a reactive iminium intermediate with the aldehyde, increasing its population. The hydrogen-bonding interaction established between the macrocycle and the electrophile was proposed as one of the reasons for the rapid formation and stabilization of this key intermediate. The experimental part of the paper was very detailed, including the reaction process of N-Boc-1,6-Diaminohexane(cas: 51857-17-1Recommanded Product: N-Boc-1,6-Diaminohexane)

N-Boc-1,6-Diaminohexane(cas: 51857-17-1) is used to prepare 1,3-Bis[6-(Boc-amino)hexyl]urea by reacting with carbonyl dichloride in the presence of triethylamine. Further, it is used as a reagent for the introduction of a C6-spacer.Recommanded Product: N-Boc-1,6-Diaminohexane

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