HPLC of Formula: 2495-35-4In 2019 ,《Enantioselective Synthesis of Biaryl Atropisomers by Pd-Catalyzed C-H Olefination using Chiral Spiro Phosphoric Acid Ligands》 appeared in Angewandte Chemie, International Edition. The author of the article were Luo, Jun; Zhang, Tao; Wang, Lei; Liao, Gang; Yao, Qi-Jun; Wu, Yong-Jie; Zhan, Bei-Bei; Lan, Yu; Lin, Xu-Feng; Shi, Bing-Feng. The article conveys some information:
The discovery of proper ligands to simultaneously modulate the reactivity and effectively control the stereoselectivity is a central topic in the field of enantioselective C-H activation. Herein, we reported the synthesis of axially chiral biaryls by Pd-catalyzed atroposelective C-H olefination. A novel chiral spiro phosphoric acid, STRIP, was identified as a superior ligand for this transformation. A broad range of axially chiral quinoline derivatives were synthesized in good yields with excellent enantioselectivities (up to 98 % ee). D. functional theory was used to gain a theor. understanding of the enantioselectivities in this reaction. The experimental part of the paper was very detailed, including the reaction process of Benzyl acrylate(cas: 2495-35-4HPLC of Formula: 2495-35-4)
Benzyl acrylate(cas: 2495-35-4) is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid, a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.HPLC of Formula: 2495-35-4
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