《Photo-Mediated Intermolecular Coupling of Alkenes with Ketones via Acyloxy Nitroso Compounds》 was written by Zheng, Danqing; Ploeger, Stefanie; Daniliuc, Constantin G.; Studer, Armido. Application of 2495-35-4 And the article was included in Angewandte Chemie, International Edition in 2021. The article conveys some information:
An atom-economic intermol. radical addition reaction of acyloxy nitroso compounds such as I to electron-deficient alkenes such as Ph vinyl ketone mediated by visible light to yield δ-acyloxy β-ketocarbonyl compound monooximes such as II is reported. The starting nitroso derivatives are readily prepared by oxidation of the corresponding oximes prepared from ketones and the overall transformation represents an oxidative coupling of a ketone with a Michael acceptor. The cascade proceeds smoothly under mild conditions, providing a series of valuable functionalized oximes in moderate to good yields. Mechanistic studies suggest that these cascades proceed via addition/coupling processes that are controlled by the persistent radical effect (PRE) with NO acting as the persistent species. After reading the article, we found that the author used Benzyl acrylate(cas: 2495-35-4Application of 2495-35-4)
Benzyl acrylate(cas: 2495-35-4) has been used in preparation of high refractive index polyacrylates. Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.Application of 2495-35-4
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Ester – Wikipedia,
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