《Diastereodivergent Intermolecular 1,2-Diamination of Unactivated Alkenes Enabled by Iodine Catalysis》 was written by Minakata, Satoshi; Miwa, Hayato; Yamamoto, Kenya; Hirayama, Arata; Okumura, Sota. Formula: C5H11NO2This research focused onvicinal diamine diastereoselective preparation; iodine catalyst stereoselective diamination alkene nitrobenzenesulfonamide chlorosulfamide; diastereodivergent diamination internal alkene iodine catalyst nitrobenzenesulfonamide chlorosulfamide. The article conveys some information:
The stereospecific, substrate (nitrogen source)-controlled intermol. anti- and syn-1,2-diaminations of unactivated alkenes using iodine as the catalyst is reported. The combined use of the two potential methods provides access to both diastereomers of 1,2-diamines from E- and Z-alkenes, and the resulting products can be readily converted into free vicinal diamines. In the experiment, the researchers used many compounds, for example, tert-Butyl carbamate(cas: 4248-19-5Formula: C5H11NO2)
tert-Butyl carbamate(cas: 4248-19-5) belongs to anime. In organic chemistry, amines are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (NH3), wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group (these may respectively be called alkylamines and arylamines; amines in which both types of substituent are attached to one nitrogen atom may be called alkylarylamines).Formula: C5H11NO2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics