Jovanovic, Dragana; Stanojkovic, Jovana; Halilovic, Dzeneta; Kolasinac, Rejhana; Kop, Tatjana J.; Bjelakovic, Mira S.; Milic, Dragana R. published their research in Journal of the Serbian Chemical Society in 2021. The article was titled 《Fulleropyrrolidines with orthogonally flexible substituents – synthesis and electrochemical properties》.Name: N-Boc-1,6-Diaminohexane The article contains the following contents:
A large series of disubstituted fulleropyrrolidines I [R1 = (CH2)6, (CH2)10, (CH2)3O(CH2)2O(CH2)2O(CH2)3; R2 = H, C9H19, 4-O2NC6H4, etc.] was synthesized and analyzed by cyclic voltammetry. The three main groups of target compounds differ by a flexible N-chain, while their further diversity was achieved by introduction of various rigid, aryl substituents at pyrrolidine carbon. Some dialkyl analogs were also designed for comparison, a standard [3 + 2]-cycloaddition of in situ generated azomethine ylides to C60 afforded a variety of disubstituted fulleropyrrolidines. Furthermore, a set of dumbbell-shaped di(fulleropyrrolidine) derivatives containing rigid fumaryl or isophthaloyl diamide platform II [R1 = (CH2)6; R2 = H, C9H19] and III [R1 = (CH2)6, (CH2)3O(CH2)2O(CH2)2O(CH2)3; R2 = H, Ph, 2-MeOC6H4, 3-MeOC6H4, 4-MeOC6H4] was prepared with aim of investigating a long-range effect of second fulleropyrrolidine moiety on their electrochem. properties. All compounds were fully characterized by comparative anal. of spectral data, while examination of electrochem. properties was performed on representative samples, distinguished by main structural subunits. All compounds expressed quite similar electron-accepting ability, lower than C60, but higher in comparison to structurally similar N-methylfulleropyrrolidine. The experimental part of the paper was very detailed, including the reaction process of N-Boc-1,6-Diaminohexane(cas: 51857-17-1Name: N-Boc-1,6-Diaminohexane)
N-Boc-1,6-Diaminohexane(cas: 51857-17-1) can be used as a linear hexyl spacer (C6-spacer) to synthesize biodegradable poly(disulfide amine)s for gene delivery, a multifunctional dendrimer for theranostics and so on.Name: N-Boc-1,6-Diaminohexane
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