SDS of cas: 2495-35-4In 2020 ,《Silyl Radical-Mediated Activation of Sulfamoyl Chlorides Enables Direct Access to Aliphatic Sulfonamides from Alkenes》 was published in Journal of the American Chemical Society. The article was written by Hell, Sandrine M.; Meyer, Claudio F.; Laudadio, Gabriele; Misale, Antonio; Willis, Michael C.; Noel, Timothy; Trabanco, Andres A.; Gouverneur, Veronique. The article contains the following contents:
Single electron reduction is more challenging for sulfamoyl chlorides than sulfonyl chlorides. However, sulfamoyl and sulfonyl chlorides can be easily activated by Cl-atom abstraction by a silyl radical with similar rates. This latter mode of activation was therefore selected to access aliphatic sulfonamides, applying a single-step hydrosulfamoylation using inexpensive olefins, tris(trimethylsilyl)silane, and photocatalyst Eosin Y. This late-stage functionalization protocol generates mols. as complex as sulfonamide-containing cyclobutyl-spirooxindoles for direct use in medicinal chem. In the part of experimental materials, we found many familiar compounds, such as Benzyl acrylate(cas: 2495-35-4SDS of cas: 2495-35-4)
Benzyl acrylate(cas: 2495-35-4) is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid, a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.SDS of cas: 2495-35-4
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