《Ligand-Enabled γ-C(sp3)-H Olefination of Free Carboxylic Acids》 was written by Ghosh, Kiron Kumar; Uttry, Alexander; Mondal, Arup; Ghiringhelli, Francesca; Wedi, Philipp; van Gemmeren, Manuel. Product Details of 2495-35-4 And the article was included in Angewandte Chemie, International Edition in 2020. The article conveys some information:
The authors report the ligand-enabled C-H activation/olefination of free carboxylic acids in the γ-position. Through an intramol. Michael addition, δ-lactones were obtained as products. Two distinct ligand classes are identified that enable the challenging palladium-catalyzed activation of free carboxylic acids in the γ-position. The developed protocol features a wide range of acid substrates and olefin reaction partners and is applicable on a preparatively useful scale. Insights into the underlying reaction mechanism obtained through kinetic studies are reported. In addition to this study using Benzyl acrylate, there are many other studies that have used Benzyl acrylate(cas: 2495-35-4Product Details of 2495-35-4) was used in this study.
Benzyl acrylate(cas: 2495-35-4) is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid, a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.Product Details of 2495-35-4
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