《Enantioselective Pallada-Electrocatalyzed C-H Activation by Transient Directing Groups: Expedient Access to Helicenes》 was published in Angewandte Chemie, International Edition in 2020. These research results belong to Dhawa, Uttam; Tian, Cong; Wdowik, Tomasz; Oliveira, Joao C. A.; Hao, Jiping; Ackermann, Lutz. Category: esters-buliding-blocks The article mentions the following:
Asym. pallada-electrocatalyzed C-H olefinations were achieved through the synergistic cooperation with transient directing groups. The electrochem., atroposelective C-H activations were realized with high position-, diastereo-, and enantio-control under mild reaction conditions to obtain highly enantiomerically-enriched biaryls and fluorinated N-C axially chiral scaffolds. Our strategy provided expedient access to, among others, novel chiral BINOLs, dicarboxylic acids and helicenes of value to asym. catalysis. Mechanistic studies by experiments and computation provided key insights into the catalyst’s mode of action. In addition to this study using Benzyl acrylate, there are many other studies that have used Benzyl acrylate(cas: 2495-35-4Category: esters-buliding-blocks) was used in this study.
Benzyl acrylate(cas: 2495-35-4) has been used in preparation of high refractive index polyacrylates. Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.Category: esters-buliding-blocks
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics