Chen, Yuan; Fu, Lulu; Sun, Baobao; Qian, Cheng; Pangannaya, Srikala; Zhu, Hong; Ma, Jing; Jiang, Juli; Ni, Zhigang; Wang, Ruibing; Lu, Xiancai; Wang, Leyong published the artcile< Selection of Planar Chiral Conformations between Pillar[5,6]arenes Induced by Amino Acid Derivatives in Aqueous Media>, COA of Formula: C8H18ClNO2, the main research area is selection planar chiral conformation pillararene induced amino acid derivative; amino acids; chiral conformations; chiral induction; chiral inversion; pillararenes.
Chiral α-amino acids play critical roles in the metabolic process in nearly all life forms. So far, chiral recognition of α-amino acids has mainly focused on the determination of L/D enantiomers. Herein, selection of planar chiral conformations between water-soluble pillar[5]arene WP5 and pillar[6]arene WP6 was observed due to α-side chain or Et ester moieties of L-α-amino acid Et ester hydrochlorides binding with WP5 and WP6, resp. Therefore, α-side chain and Et ester moieties of L-α-amino acid Et ester hydrochlorides were recognized by observing the induced CD signal and its inversion. This is a rare example of being able to detect the chiral region around α-carbon of a chiral α-amino acid mol.
Chemistry – A European Journal published new progress about Chiral amino acids Role: ANT (Analyte), ANST (Analytical Study). 2743-40-0 belongs to class esters-buliding-blocks, and the molecular formula is C8H18ClNO2, COA of Formula: C8H18ClNO2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics