Bihani, Manisha; Bora, Pranjal P.; Nachtegaal, Maarten; Jasinski, Jacek B.; Plummer, Scott; Gallou, Fabrice; Handa, Sachin published the artcile< Microballs Containing Ni(0)Pd(0) Nanoparticles for Highly Selective Micellar Catalysis in Water>, COA of Formula: C11H15NO3, the main research area is nickel palladium nanoparticle selective micellar catalysis water.
Both Ni(0) complexes and nanoparticles (NPs) are unstable in water, which poses a significant hindrance to their application in aqueous synthetic catalysis. To overcome these barriers, ligated Ni(0) nanoparticles (diameter <1 nm) containing a min. amount of Pd(0) in the microballs formed of amphiphile PS-750-M are developed and applied in the highly selective carbamate cleavage. Selectivity and functional group tolerance are thoroughly investigated. Control experiments revealed the importance of an individual component of the nanocatalyst. Use of our proline-based amphiphile PS-750-M is critical for achieving microball architecture, the stability of nanoparticles, and desired catalytic activity. Once formed, microballs can be isolated and stored at ambient temperature Catalyst is thoroughly characterized by XPS, SEM, high-resolution transmission electron microscopy, thermogravimetric anal., IR, and cyclic voltammetry. For selective catalysis, zero oxidation state of both Ni and Pd is crucial. On the basis of catalyst characterization and control experiments, the plausible reaction mechanism is proposed. ACS Catalysis published new progress about Binding energy. 34637-22-4 belongs to class esters-buliding-blocks, and the molecular formula is C11H15NO3, COA of Formula: C11H15NO3.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics