《Photochemistry of two β,β’-epoxy ketones, 3-oxatricyclo[3.2.1.02,4]octan-8-one and 3-oxatricyclo[3.3.1.02.4]nonan-9-one. Intramolecular reactions of α,β-unsaturated aldehydo ketenes》 was published in Journal of Organic Chemistry in 1978. These research results belong to Ayral-Kaloustian, Semiramis; Wolff, Steven; Agosta, William C.. COA of Formula: C8H14O3 The article mentions the following:
Photolysis of epoxy ketone I in C6H6 leads to OHCCH:CHCH2CH2CH:CO (II) and β-lactone III as primary products. Subsequent addition of MeOH furnishes IV and V. Secondary photolysis of II yields the cycloaddition product VI. Photolysis of I in C6H6 containing 3% MeOH gives IV directly, along with VII. Similar irradiation of epoxy ketone VIII leads to OHCCH:CH(CH2)3CH:CO, which reacts with MeOH to give the aldehydo esters IX and X. The results came from multiple reactions, including the reaction of Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8COA of Formula: C8H14O3)
Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones.COA of Formula: C8H14O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics