Zhang, Junjie; Wang, Huanxia; Ma, Yun; Wang, Youming; Zhou, Zhenghong; Tang, Chuchi published the artcile< CaF2 catalyzed SN2 type chlorodehydroxylation of chiral secondary alcohols with thionyl chloride: a practical and convenient approach for the preparation of optically active chloroalkanes>, Category: esters-buliding-blocks, the main research area is chloroalkane chiral preparation; calcium fluoride catalyst chlorodehydroxylation chiral secondary alc thionyl chloride.
A CaF2 catalyzed chlorodehydroxylation of chiral secondary alcs. with thionyl chloride has been developed. The chlorination reaction is effective for a wide range of alcs., generating the corresponding chloroalkanes in good yield with high optical purity with inversion of the original configuration of the alc.
Tetrahedron Letters published new progress about Chlorination. 617-55-0 belongs to class esters-buliding-blocks, and the molecular formula is C6H10O5, Category: esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics