《Supramolecularly regulated copper-bisoxazoline catalysts for the efficient insertion of carbenoid species into hydroxyl bonds》 was published in Chemical Communications (Cambridge, United Kingdom) in 2020. These research results belong to Iniesta, Ester; Vidal-Ferran, Anton. Recommanded Product: 609-14-3 The article mentions the following:
The catalytic insertion of copper carbenoids into O-H bonds affords synthetically useful α-alkyl/aryl-α-alkoxy/aryloxy derivatives Herein, the design, preparation and application of supramolecularly regulated copper(I) complexes of bisoxazoline ligands is reported. The catalytic performance of these systems can be modulated using an external mol. (i.e. the regulation agent), which interacts with a polyethyleneoxy chain on the ligand (i.e. the regulation site) via supramol. interactions. This approach was applied to an array of structurally diverse alcs. (cycloalkyl, alkyl and aryl derivatives). Moreover, the authors used this methodol. to synthesize advanced synthetic intermediates of biol. relevant compoundsEthyl 2-methyl-3-oxobutanoate(cas: 609-14-3Recommanded Product: 609-14-3) was used in this study.
Ethyl 2-methyl-3-oxobutanoate(cas: 609-14-3) belongs to ketone compounds. Ketones are highly reactive, although less so than aldehydes, to which they are closely related. Much of their chemical activity results from the nature of the carbonyl group. Ketones readily undergo a wide variety of chemical reactions.Recommanded Product: 609-14-3
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