Ding, Zekun; Luo, Xiaosheng; Ma, Yibin; Chen, Heshan; Qiu, Saifeng; Sun, Guosheng; Zhang, Wan; Yu, Chao; Wu, Zhenliang; Zhang, Jianbo published the artcile< Eco-friendly synthesis of 5-hydroxymethylfurfural (HMF) and its application to the Ferrier-rearrangement reaction>, SDS of cas: 4098-06-0, the main research area is hydroxymethylfurfural green synthesis; Ferrier rearrangement synthesis hydroxymethylfurfural unsaturated glycoside.
5-Hydroxymethylfurfural was conveniently synthesized by dehydration of D-fructose in a good yield. To further build bioactive derivatives from 5-hydroxymethylfurfural, 2,3-unsaturated glycosides were directly obtained through the Ferrier-rearrangement reaction of various glycals. Noticeably, a solid acid catalyst was successfully applied in the preparation of 5-hydroxymethylfurfural and then recycled to promote the Ferrier-rearrangement reaction, making it possible to achieve two steps of reaction in an eco-friendly manner through the simple process.
Journal of Carbohydrate Chemistry published new progress about Antitumor agents. 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, SDS of cas: 4098-06-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics