Zhang, Hui; Shang, Yan; Zhao, Hong; Wang, Xuan; Han, Baozhong; Li, Zesheng published the artcile< Further discussion on the reaction behaviour of triallyl isocyanurate in the UV radiation cross-linking process of polyethylene: a theoretical study>, Application of C18H26O6, the main research area is triallyl isocyanurate polyethylene crosslinking UV radiation; UV radiation cross-linking polyethylene process; transition states; triallyl isocyanurate.
Further theor. investigation on the reaction behavior of triallyl isocyanurate (TAIC) in the UV radiation crosslinking process of polyethylene (PE) is accomplished by d. functional theory for high voltage cable insulation materials. The reaction potential energy information of the 13 reaction channels at B3LYP/6-311 + G(d,p) level are identified. These have been explored that the TAIC take part in the reaction behavior on ground state during UV radiation crosslinking process and TAIC intra-mol. isomerization reaction itself. In addition, the results show that the effect of multiplication and acceleration for the crosslinking reaction of trimethylolpropane trimethacrylate(TMPTMA) would be better than that of TAIC. It has further clarified the reasons why UV radiation crosslinking reaction of PE had been initiated by benzophenone (Bp), and the TAIC or TMPTMA needed to take part. The results obtained in the present study could directly guide both the optimization of UV radiation crosslinking PE process and the development of the insulation material of high-voltage cable in real application.
Royal Society Open Science published new progress about Band gap. 3290-92-4 belongs to class esters-buliding-blocks, and the molecular formula is C18H26O6, Application of C18H26O6.
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