Zhang, Huihua; Morshedi, Mahbod; Kodikara, Mahesh S.; Moxey, Graeme J.; Wang, Genmiao; Wang, Huan; Quintana, Cristobal; Stranger, Rob; Zhang, Chi; Cifuentes, Marie P.; Humphrey, Mark G. published the artcile< Synthesis, Optical, Electrochemical, and Theoretical Studies of Dipolar Ruthenium Alkynyl Complexes with Oligo(phenylenevinylene) Bridges>, Quality Control of 112-63-0, the main research area is dipolar ruthenium alkynyl oligophenylenevinylene bridged preparation crystal mol structure; electrochem redox quadratic nonlinear optical property alkynyl ruthenium oligophenylenevinylene; mol structure calculation alkynyl ruthenium oligophenylenevinylene bridged; computational chemistry; electrochemistry; nonlinear optics; organometallic chemistry; transition metals.
The syntheses of oligo(p-phenylenevinylene)s (OPVs) end-functionalized with a ligated ruthenium alkynyl unit as a donor and a nitro as acceptor, namely trans-[Ru{CC-1-C6H4-4-(E)-CH:CH-1-C6H2-2,5-Et2-4-(E)-CH:CH-1-C6H2-2,5-Et2-4-(E)-CH:CH-1-C6H4-4-NO2}Cl(dppe)2] (Ru4), trans-[Ru{CC-1-C6H4-4-(E)-CH:CH-1-C6H2-2,5-Et2-4-(E)-CH:CH-1-C6H2-2,5-Et2-4-(E)-CH:CH-1-C6H2-2,5-(n-hexyl)2-4-(E)-CH:CH-1-C6H2-2,5-(n-hexyl)2-4-(E)-CH:CH-1-C6H4-4-NO2}Cl(dppe)2] (Ru6), and trans-[Ru{CC-1-C6H4-4-(E)-CH:CH-1-C6H2-2,5-Et2-4-(E)-CH:CH-1-C6H2-2,5-Et2-4-(E)-CH:CH-1-C6H2-2,5-(n-hexyl)2-4-(E)-CH:CH-1-C6H2-2,5-(n-hexyl)2-4-(E)-CH:CH-1-C6H2-2,5-(2-ethyl-n-hexyl)2-4-(E)-CH:CH-1-C6H2-2,5-(2-ethyl-n-hexyl)2-4-(E)-CH:CH-1-C6H4-4-NO2}Cl(dppe)2] (Ru8), are reported, together with those of precursor alkynes. Their electrochem. properties were assessed by cyclic voltammetry (CV), their linear optical and quadratic nonlinear optical (NLO) properties assayed by UV/Vis-NIR spectroscopy and hyper-Rayleigh scattering studies at 1064 nm, resp., and their linear optical properties in the formally RuIII state examined by UV/Vis-NIR spectroelectrochem. Computational studies employing time-dependent d. functional theory were undertaken on model complexes to rationalize the optical observations.
ChemPlusChem published new progress about Crystal structure. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Quality Control of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics