Yao, Wang; Wang, Hao; Zeng, Jing; Wan, Qian published the artcile< Practical synthesis of 2-deoxy sugars via metal free deiodination reactions>, Category: esters-buliding-blocks, the main research area is solvent effect iodination deiodination dilauroyl peroxide catalyst glycoside preparation; deoxyglycoside preparation reductive deiodination lauroyl peroxide catalyst glycoside preparation.
2-Deoxy-glycosides, in which the C-2 hydroxyl group is replaced with a hydrogen atom, are important motifs in numerous bioactive natural products and pharmaceutical mols. Herein, an improved dilauroyl peroxide-mediated radical deiodination reaction by using cyclohexane and Et acetate as co-solvent is reported. This is an environmentally benign protocol, which operates smoothly under mild conditions and allows efficient preparation of a series of 2-deoxy-glycosides in up to 98% yields.
Journal of Carbohydrate Chemistry published new progress about Deiodination. 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Category: esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics