Feng, Wei; Zhang, Xing-Guo published the artcile< Organophosphine-free copper-catalyzed isothiocyanation of amines with sodium bromodifluoroacetate and sulfur>, Synthetic Route of 19241-24-8, the main research area is primary amine sodium bromodifluoroacetate sulfur copper iodide catalyst isothiocyanation; isothiocyanate preparation green chem.
A copper-catalyzed isothiocyanation of amines with sodium bromodifluoroacetate and sulfur in the absence of organophosphine was established. This approach represented a simple and efficient one-pot synthesis of isothiocyanates and features excellent functional group tolerance and the use of a cheap, safe and odorless sulfur source. This process could directly provided isothiocyanate analogous bioactive mols., thiocarbonyl-containing pesticides and facile construction of benzoxazole and benzimidazole frames.
Chemical Communications (Cambridge, United Kingdom) published new progress about Cyanation (isothio). 19241-24-8 belongs to class esters-buliding-blocks, and the molecular formula is C11H13NS, Synthetic Route of 19241-24-8.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics